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Soal IChO Ke-26

Ditulis oleh Redaksi chem-is-try.org pada 13-03-2009

THEORETICAL PROBLEM No 8

(9 blue points, 7 red points)

Avogadro’s Number: 6.022E23

a) An atom of 238U disintegrates by a series of [[alpha]]-decays and ß--decays until it becomes 206Pb, which is stable.

i) How many a-decays and how many ß--decays does an atom starting as

238U undergo before it becomes stable ?

ii) One of the following ten nuclides is formed from a series of

disintegrations starting at 238U. Which one ?

235U, 234U, 228Ac, 224Ra, 224Rn, 220Rn, 215Po, 212Po, 212Pb, 211Pb.

b) In a thermal neutron-induced fission process, 235U reacts with a neutron and breaks up into energetic fragments and (normally) 2-3 new neutrons.

We consider one single fission event:

235U + n -> 137Te + X + 2n

Identify the fragment X.

c) The half-life of 238U is 4.5 .E09 years, the half-life of 235U is 7.0 .E08 years

Natural uranium consists of 99.28 % 238U and 0.72 % 235U

i) Calculate the ratio in natural U betweeen the disintegration rates of these

two uranium isotopes.

ii) A mineral contains 50 weight percent uranium. Calculate the disintegration rate of 238U in 1.0 kg of this mineral.

d) We have the following radioactive sequence:

97Ru -> 97Tc -> 97Mo (stable)

Halflives: 97Ru: 2.7 days ; 97Tc: 2.6.106 years

At t= 0, a radioactive source containing only 97 Ru has a disintegration rate of 1.0.109 Bq.

i) What is the total disintegration rate of the source at t = 6.0 days ?

ii) What is the total disintegration rate of the source at t = 6000 years

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